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Conductivity/ductility relation?

Does anybody have any references to ( maybe ) a theory explaining the
relation between ductility/conductivity?

        Au  very ductile,conductive
        Cu  very conductive,ductile
        Ag  very ductile,conductive

        Fe  baddish conductivity,brittle ( cast iron )
        Pb  baddish conductivity,not ductile ( but malleable )

Or, better still, can someone mail me anything relevant?

We’ve discovered this in a recent lecture, checked some encyclopaedias, etc.
but no text we’ve had so far connect the two.

Any suggestions?

posted by admin in Uncategorized and have Comment (1)

One Response to “Conductivity/ductility relation?”

  1. admin says:

    jndbe…@scilab.uct.ac.za wrote:
    >Does anybody have any references to ( maybe ) a theory explaining the
    >relation between ductility/conductivity?

    Are you talking about electrical conductivity or thermal conductivity?
    Diamonds and some carbon fibers have terrific thermal conductivity and
    essentially no ductility.  High temperature semiconductors have *very
    large* electrical conductivity but are extremely brittle.  A number of
    superalloys based on cobalt or nickel are quite ductile, but not very
    conductive; same with some austenitic stainless steels.  

    >    Au  very ductile,conductive
    >    Cu  very conductive,ductile
    >    Ag  very ductile,conductive
    >    Fe  baddish conductivity,brittle ( cast iron )
    >    Pb  baddish conductivity,not ductile ( but malleable )

    Cast iron isn’t very pure iron.

    In metals, high defect density tends to reduce both ductility and
    conductivity but in a given alloy the effect on ductility is much greater
    than on conductivity.  Have you ever read about the experiment (I don’t
    recall exactly where I read about it) where diamond was made with a single
    carbon isotope (C-12 only) and the thermal conductivity was found to be
    much greater than in natural diamond?  Another intriguing phenomenon is
    the relation between conductivity (both thermal and electrical) and purity
    in substitutional alloy systems, such as copper/nickel.  Conductivity
    peaks at the pure metals and drops orders of magnitude for mixtures.

    >Or, better still, can someone mail me anything relevant?
    >We’ve discovered this in a recent lecture, checked some encyclopaedias,
    etc.
    >but no text we’ve had so far connect the two.

    I think the problem invariably involves quantum mechanics at the very deep
    hand-waving level. [:<8)]

    Mark Folsom